trans-Dibromidobis(tri-p-tolylarsine)palladium(II)
نویسندگان
چکیده
منابع مشابه
trans-Ethylenedi-p-phenylene diacetate
The centrosymmetric title compound, C(18)H(26)O(4), was prepared in high yield from 4-acetoxy-styrene via Ru-catalysed homo-olefin metathesis. Exclusive formation of the E-configurated isomer was observed. In the crystal, a strong C-H⋯π inter-molecular inter-action links the mol-ecules together.
متن کاملtrans-Dibromidobis(tri-p-tolylarsine)palladium(II)
In the title compound, [PdBr(2)(C(21)H(21)As)(2)], the Pd(II) ion, residing on a centre of symmetry, is coordinated by two As donor atoms [Pd-As = 2.4276 (2) Å] and two Br anions [Pd-Br = 2.4194 (2) Å] in a distorted square-planar geometry [Br-Pd-As = 87.786 (7)°]. A weak intra-molecular C-H⋯Br inter-action occurs. In the crystal structure, inter-molecular C-H⋯Br inter-actions are observed.
متن کاملtrans-Carbonylchloridobis(tri-p-tolylphosphine)rhodium(I) acetone solvate
The title compound, [RhCl(C(21)H(21)P)(2)(CO)]·C(3)H(6)O, was precipitated in trace yield from a reaction of RhCl(cod)(THP) with P(p-tol)(3) in a 1:1 acetone-d(6)/CD(3)OD solution under a hydrogen atmosphere [p-tol = p-tolyl, THP = tris-(hydroxy-meth-yl)phosphine, P(CH(2)OH)(3), and cod = 1,5-cyclo-octa-diene]. The complex displays a square-planar geometry around the Rh(I) atom. The complex mol...
متن کاملtrans-Dibromidobis[diphenyl(p-tolyl)phosphine]palladium(II)
In the title compound, [PdBr(2)(C(19)H(17)P)(2)], the Pd(II) ion resides on a centre of symmetry and is coordinated by two Br anions [Pd-Br = 2.4266 (2) Å] and two P-donor ligands [Pd-P = 2.3462 (5) Å] in a slightly distorted square-planar geometry [P-Pd-Br = 93.528 (12)°]. Weak inter-molecular C-H⋯Br hydrogen bonds link mol-ecules into chains extended in [10].
متن کاملtrans-Tetraiodidobis(tri-p-tolylphosphine oxide-κO)tin(IV)
The centrosymmetric title compound, [SnI(4)(C(21)H(21)OP)(2)], is a monomeric complex that displays a nearly octa-hedral coordination of tin(IV), with an Sn-O bond distance of 2.159 (2) Å and an average Sn-I bond distance of 2.79 (3) Å.
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2009
ISSN: 1600-5368
DOI: 10.1107/s1600536809043372